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Eight days on from their thumping win in Amsterdam, Group A leaders Napoli face Ajax again, as they seek to secure a place in the Champions League knockout stage at Stadio Maradona.
The teams reconvene on Wednesday evening, with the hosts able to assure progress by beating their Dutch counterparts for a second time; the visitors need points to stay in touch with Liverpool.
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Atletico Madrid will be looking for revenge against Club Brugge when they welcome the Belgian giants to Wanda Metropolitano in the Champions League on Wednesday night.
Club Brugge recorded a 2-0 victory when the pair locked horns last week, with the result leaving Carl Hoefkens’s side top of Group B on nine points, while Atletico are bottom of the section on three points.
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Rangers will be aiming to get themselves off the mark in this season’s Champions League when they host Liverpool on Wednesday, having suffered three straight defeats in Group A.
The Reds, meanwhile, will hope to extend their three-point gap ahead of third-placed Ajax.
The Gers’ necessity to go for the win may play into Klopp’s side’s hands as, despite their recent defensive issues, they still retain bags of pace and quality in attack.
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> How Liverpool could line up against Rangers
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Tied on three points apiece after last week’s reverse fixture in Portugal, Group B rivals Bayer Leverkusen and Porto meet again on Wednesday, with progress to the Champions League’s last-16 still up for grabs.
While surprise package Club Brugge are currently sprinting off into the distance, both sides join Atletico Madrid six points behind the leaders after Leverkusen lost 2-0 at Estadio Dragao last time out – a result which prompted a change of coach for Die Werkself.
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Barcelona will be looking to give their Champions League knockout-round hopes a huge boost when they welcome Inter Milan to Camp Nou for a key encounter on Wednesday night.
The Catalan outfit are third in Group C, three points behind second-placed Inter, with the Italian giants recording a 1-0 victory when the two teams locked horns at San Siro last week.
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Tottenham Hotspur will welcome Eintracht Frankfurt and their masses of supporters to North London on Wednesday for an important matchday four encounter in the UEFA Champions League.
Both clubs sit on four points in Group D with Spurs only currently above their German opponents on goal difference, occupying the second qualifying spot for the last 16.
With defeat being unacceptable and a draw hardly ideal, Spurs must find something to take all three points, and they may just have the individual quality to snatch a result in a group which has produced very few goals so far.
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> How Spurs could line up against Frankfurt
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Seeking to pick up a fourth consecutive home victory, Sporting Lisbon go head to head with Marseille to the Estadio Jose Alvalade in Group D of the Champions League on Wednesday.
The Ligue 1 outfit finally got their European campaign underway last week when they comfortably edged out Ruben Amorim’s side on home turf and will be looking to continue in the same vein.